Gerben's answer probably is correct, but there are some interesting discrepancies in Atmel datasheets for various models of the ATmega168 and ATmega328, as outlined below.
Some Atmel datasheets refer to ADC6 and ADC7 as PE2 and PE3, while others just refer to them as ADC6 and ADC7.
Regarding port E, the 2014 ATmega168PA and 2015 ATmega168 datasheets say nothing, don't list any of PE0 to PE3, and don't specify port membership for ADC6 and ADC7. They show pins 3 and 6 on the LQFP as Gnd and Vcc, vs PE0 and PE1 as in the ATmega168PB sheet.
Regarding port E, the 2015 ATmega168PB datasheet says:
Table 15-12. Port E Pins Alternate Functions
Port Pin Alternate Function
PE3 ADC7 (ADC Input Channel 7)
PE2 ADC6 (ADC Input Channel 6)
PE1 NONE
PE0 ACO (AC Output Channel 0)
Regarding port E, the 2016 ATmega168PB datasheet, Atmel-42176G-ATmega48PB/88PB/168PB_Datasheet_Complete-03/2016, says the following
and also lists several Alternate Functions while referring to
Timer/Counters 3 and 4 (although there seem to be no registers in the
register summary relevant to such Timer/Counters):
"Port E is an 4-bit bi-directional I/O port with internal pull-up
resistors (selected for each bit). The Port E output buffers have
symmetrical drive characteristics with both high sink and source
capability. As inputs, Port E pins that are externally pulled low will
source current if the pull-up resistors are activated. The Port E pins
are tri-stated when a reset condition becomes active, even if the clock is not running."
Table 19-12. Port E Pins Alternate Functions
Port Pin Alternate Function
PE3 ADC7 (ADC Input Channel 7)
T3 (Timer/Counter 3 External Counter Input) & PCINT27
PE2 ADC6 (ADC Input Channel 6)
ICP3 (Timer/Counter3 Input Capture Input)
SS1 (SPI1 Bus Master Slave select) & PCINT26
PE1 T4 (Timer/Counter 4 External Counter Input)
SCL1 (2-wire Serial1 Bus Clock Line) & PCINT25
PE0 ACO (AC Output Channel 0)
ICP4 (Timer/Counter4 Input Capture Input)
SDA1 (2-wire Serial1 Bus Data Input/Output Line) & PCINT24