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I have an arduino mega that will be communicating through serial to a pc. One of the things I want it to tell the pc is whether or not it is connected to a wall power to 12V converter (where there is a switch between the arduino and the wall power). I was just wondering if there was a way to do that in software without having any additional hardware.
Thanks!
No, you can't do it without extra hardware.
You need to pass VIN through a voltage divider so it sits within 0-5V when powered by 12V, then feed that into an ADC input. Protect the on-board voltage regulator with a diode between 5V (anode) and VIN (cathode). Then you can measure the voltage on VIN and make a decision on if it is around 4.5V or 11.5V
A 22K/10K voltage divider will reduce 12V down to 3.75V, which gives plenty of "headroom" for over-voltage situations (where your 12V unregulated power supply actually provides, say, 15V):
